81. Metal carbonyl complexes are studied in the context of potential therapeutic CO delivery in medicine as carbon monoxide-releasing molecules (CORMs). Predict which CO ligand in the following complexes has the highest CO stretching frequency (νCO in IR spectroscopy).
(A) bridging CO of Fe2(CO)9
(B) [Mn(CO)6]+
(C) (CO)5Cr=C(OMe)Ph (a Fischer carbene complex)
(D) [V(CO)6]-
(E) fac-Cr(CO)3(NH3)3

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統計: A(0), B(0), C(0), D(0), E(1) #3854103

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